The pentanuclear Fe~Ⅱ cluster [(C_5H_4)_6Fe_5]~(2-) : bringing together ferrocene sandwiches and homoleptic Fe~Ⅱ-cyclopentadienyl σ-complexes

Ingeborg Saenger; Julia B. Heilmann; Michael Bolte; Hans-Wolfram Lerner; Matthias Wagner

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The pentanuclear Fe~Ⅱ cluster [(C_5H_4)_6Fe_5]~(2-) : bringing together ferrocene sandwiches and homoleptic Fe~Ⅱ-cyclopentadienyl σ-complexes

机译：五核Fe〜Ⅱ簇[[C_5H_4）_6Fe_5]〜（2-）：将二茂铁三明治和均质的Fe〜Ⅱ-环戊二烯基σ-络合物聚集在一起

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Reaction of [(fc)_3(Li)_6·(TMEDA)_2] with FeCl_2 gives the pentanuclear iron complex [(fc)_3(Fe)_2(Li)_2·(TMEDA)_2] featuring two ferra ferrocenophane moieties bridged by a 1, 1'-ferrocenediyl unit; the non-ferrocene Fe~Ⅱ ions are tetra-coordinate and adopt a high-spin state.

机译：[（fc）_3（Li）_6·（TMEDA）_2]与FeCl_2的反应产生了五核铁络合物[（fc）_3（Fe）_2（Li）_2·（TMEDA）_2]，其特征在于两个铁氧亚铁花环烷氧基桥连1，1'-二茂铁基单元；非二茂铁Fe〜Ⅱ离子为四配位态，呈高自旋态。

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来源
《Chemical Communications》 |2006年第19期|p.2027-2029|共3页
作者
Ingeborg Saenger; Julia B. Heilmann; Michael Bolte; Hans-Wolfram Lerner; Matthias Wagner;
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Institut fuer Anorganische Chemie, J. W. Goethe-Universitaet Frankfurt, Marie-Curie-Strasse 11, D-60439 Frankfurt (Main), Germany;

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正文语种 eng
中图分类化学;
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The pentanuclear Fe~Ⅱ cluster [(C_5H_4)_6Fe_5]~(2-) : bringing together ferrocene sandwiches and homoleptic Fe~Ⅱ-cyclopentadienyl σ-complexes

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