Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br-Mg exchange

Taramatee Ramnial; Stephanie A. Taylor; Jason A. C. Clyburne; Charles J. Walsby

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Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br-Mg exchange

机译：离子溶剂中的格氏试剂：电子转移反应和容易进行溴化镁交换的证据

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Grignard reagents form persistent solutions in phosphonium ionic liquids possessing O-donor anions and these solutions are excellent reaction media for electron transfer processes and transmetallation reactions.

机译：格氏试剂在具有O-给体阴离子的离子液体中形成持久溶液，这些溶液是电子转移过程和金属转移反应的出色反应介质。

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《Chemical Communications》 |2007年第20期|p.2066-2068|共3页
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Taramatee Ramnial; Stephanie A. Taylor; Jason A. C. Clyburne; Charles J. Walsby;
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Department of Chemistry, Simon Eraser University, 8888 University Drive, Burnaby, British Columbia, Canada V5A 1S6;

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正文语种 eng
中图分类化学;
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入库时间 2022-08-17 13:28:25

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机译：新观点：I. 13C NMR光谱法定量测定化合物比例；二。有证据表明，将格氏试剂添加到脂肪醛中不涉及单电子转移过程。
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8. Solvent Dynamical Effects in Electron Transfer: Evaluation of Electronic Matrix Coupling Elements for Metallocene Self-Exchange Reactions [R] . McManis, G. E., Nielson, R. M., Gochev, A., 1989

机译：电子转移中的溶剂动力学效应：茂金属自交换反应的电子基质偶联元素评价

Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br-Mg exchange

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