Preparation and characterization of noble metal modified titanium dioxide hollow spheres - new insights concerning the light trapping efficiency

摘要

Titanium dioxide hollow spheres (TiO2-HSs) were fabricated by applying carbon spheres (CSs) as templates, which were eliminated by calcination. The most suitable TiO2 was selected and an attempt was made to further increase its photocatalytic activity via noble metal (Au and Pt, at 0.25 wt%) deposition. The photocatalytic efficiency was determined by the decomposition of phenol and oxalic acid under both UV-A and visible light irradiation. It was established, that both the unique morphology and the presence of noble metals contributed to the photocatalytic activity gain compared to the solid spherical reference. For the elucidation of the observed phenol degradation performance under UV-A light irradiation, new insights were proposed: within the TiO2 samples the ratio of HSs with enhanced light trapping properties were demonstrated, and the data was compared to the observed photocatalytic activities and a direct correlation was found.