High electrostrictive coefficient Q33 in lead-free Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 piezoelectric ceramics

摘要

In this study, the electrostrictive effect in Ba(ZrTi)O-x(BaCa)TiO (BZT-xBCT, x = 0.4, 0.5, and 0.6) ceramics was investigated to gain understanding of their high piezoelectric activity. The electrostrictive coefficient Q of the BZT-xBCT ceramics was observed to be around 0.04 m/C, twice that reported for Pb(Zr,Ti)O-based ceramics. The Q was found to be quite stable with respect to temperature and composition for the BZT-xBCT ceramics. The addition of Fe dopant to the ceramics greatly decreased their Curie temperature without affecting their Q, which remained 0.04 m/C. Moreover, a high and hysteresis-free electric-field-induced strain was obtained for 2 at. % Fe-doped BZT-0.5BCT ceramics at room temperature, caused by their high Q coefficient and lower-than-room-temperature Curie temperature. The small-signal M coefficient of 2 at. % Fe-doped BZT-0.5BCT ceramics was found to be 1.5 × 10 m/V (0.32 × 10 m/V for undoped counterpart). These results indicate that 2 at. % Fe-doped BZT-0.5BCT ceramics have great potential as alternatives for hard Pb(Zr,Ti)O ceramics in actuator applications, where reproducible and non-hysteretic deformation responses are required.