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A hydrogen sensor based on tunneling between palladium clusters

机译:基于钯簇之间隧穿的氢传感器

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摘要

We describe nanocluster based tunneling sensors for detecting hydrogen. Pd clusters with diameters ranging from 3.5 to 6 nm are deposited between a pair of contacts until a predetermined resistance between the contacts is obtained. We demonstrate that the conduction through the cluster film is dominated by tunneling gaps. Upon exposure to hydrogen, the clusters expand, reducing the average size of the gaps and reducing the measured resistance. The sensor response as a function of external hydrogen pressure is described, for different cluster sizes and different operating temperatures, by a simple model with a single physically meaningful fitting parameter.
机译:我们描述了用于检测氢的基于纳米团簇的隧穿传感器。在一对触点之间沉积直径范围为3.5至6 nm的Pd簇,直到获得触点之间的预定电阻。我们证明了通过簇状薄膜的传导主要由隧穿间隙决定。暴露于氢气后,团簇膨胀,从而减小了间隙的平均尺寸并降低了测得的电阻。通过具有单个物理意义上合适的拟合参数的简单模型,针对不同的簇尺寸和不同的工作温度描述了传感器响应作为外部氢压力的函数。

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