Performance improvement of micro-fuel cell by manipulating the charged diffuse layer

摘要

A fuel cell device is presented based on a counter-flow microfluidic fuel cell (CFMFC) with nano-porous electrodes by developing an advection flux of ions within the electric double layer (EDL). Typically, in a microfluidic fuel cell, advection in the EDL is negligible because the near wall electrolyte velocity is zero. However, by using nano-pores, a non-negligible ion flux due to advection can be developed in the charged regions of the EDL which affects the structure of the EDL. In this article, we use a mathematical model to study how advection in the EDL affects the kinetic performance of fuel cells. Our model predicts that the peak power density can be increased by more than 2 fold in a CFMFC using this approach to kinetic enhancement.