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Surface roughness effect on the metallic bipolar plates of a proton exchange membrane fuel cell

机译:表面粗糙度对质子交换膜燃料电池金属双极板的影响

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Proton exchange membrane fuel cells (PEMFCs) is a promising candidate as energy systems. However, the stability and lifetime of cells are still important issues. The effect of surface roughness on metallic bipolar plate is discussed in this paper. Various roughness on the bulk surface are obtained by the sandblasting method. The grain sizes of sand are selected as 50,100 and 200 μm. The Ac impedance experiment results show that the bipolar plate roughness and carbon paper porosity are well matched when the surface roughness is within 1-2 urn. Superior condition decreases the contact resistance loss in the fuel cell. The high frequency resistance of the coarse surface was larger than that of the substrate by around 5 mΩ. Furthermore, a new arc was formed at the low frequency region. Hence, the unmatch roughness condition of the bipolar plate significantly increases the contact resistance and mass transfer resistance. This paper develops a sequential approach to study an optimum surface roughness by combining the whole performance (Ⅰ-Ⅴ) curve and AC impedance result. It benefits us to quantify the contact and mass transfer resistance exists in the PEMFC. The proposed surface treatment improves the surface effect and promotes the implement of potential metallic bipolar plate in near future.
机译:质子交换膜燃料电池(PEMFC)是有前途的候选能源系统。然而,电池的稳定性和寿命仍然是重要的问题。本文讨论了表面粗糙度对金属双极板的影响。通过喷砂法在块体表面上获得各种粗糙度。沙子的粒度选择为50,100和200μm。交流阻抗实验结果表明,当表面粗糙度在1-2微米以内时,双极板的粗糙度和复写纸的孔隙率具有很好的匹配性。优越的条件降低了燃料电池中的接触电阻损失。粗糙表面的高频电阻比基板的高频电阻大5mΩ。此外,在低频区域形成了新的电弧。因此,双极板的不匹配粗糙度条件显着增加了接触电阻和传质电阻。本文结合整体性能(Ⅰ-Ⅴ)曲线和交流阻抗结果,提出了一种顺序法研究最佳的表面粗糙度。量化PEMFC中存在的接触和传质阻力对我们有益。所提出的表面处理改善了表面效果并在不久的将来促进了潜在的金属双极板的实现。

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