Role of vermiculite and zirconium-vermiculite on the formation of zircon-cordierite nanocomposites

摘要

The Zr~(4+)-vermiculites were studied in their new role of the zircon precursor in the clay minerals mixtures which were prepared for firing of the zircon-cordierite nanocomposites. Currently there is a lack of data available about the structure of Zr~(4+)-vermiculites, on which this study was performed. The modeling of the arrangement of interlayer material in the Zr~(4+)-vermiculite led to new findings that water molecules are attracted more strongly by Mg~(2+) cations than by Zr-tetrameric cations, and that both the tetrameric cations [Zr4(OH)_(14)(H_2O)_(10)]~(2+) and [Zr_4(OH)_8(H_2O)_(16)]~(8+) may be present in the interlayer space of the Zr~(4+)-vermiculites. Vermiculites from two different localities Czech Republic (Verml) and from Brazil (Verm2) were intercalated using the zirconyl chloride (ZrOCl_2-30% solution in HCl) and the prepared Zr~(4+)-vermiculites were designated as Zr~(4+)-Verml and Zr~(4+)-Verm2, respectively. Influence of the Zr~(4+)-Verml and Zr~(4+)-Verm2 in the mixtures of clay minerals on the properties of zircon-cordierite nanocomposites were investigated by their comparison with the properties of the zircon-cordierite nanocomposites, which were prepared using saturation of the clay minerals mixtures containing Verml and Verm2 with the zirconyl chloride (ZrOCl_2-30% solution in HCl). The zircon-cordierite nanocomposites fired from the clay mineral mixtures containing Zr~(4+)-Verml and Zr~(4+)-Verm2 showed a maximum porosity of P = 58 and 60%, skeletal density SD = 3.2 and 3.6, and the smallest pores with a median pores diameter MDP = 18 and 15 μm, respectively, in comparison with the zircon-cordierite nanocomposites fired from the clay mineral mixtures containing Verml and Verm2 and saturated with zirconyl chloride solution. The type of vermiculite Verml or Verm2 in the clay mineral mixtures did not affect the contents of the crystalline mineral phases in cordierite and zircon-cordierite nanocomposites.