Absolute concentration of free volume-type defects in ultrafine-grained Fe prepared by high-pressure torsion

摘要

A maximum excess volume ΔV/V ≈ 1.9 × 10⁻³ in ultrafine-grained Fe prepared by high-pressure torsion is determined by measurements of the irreversible length change upon annealing employing a high-resolution differential dilatometer. Since dislocations and equilibrium-type grain boundaries cannot fully account for the observed released excess volume, the present study yields evidence for a high concentration of free volume-type defects inherent to nanophase materials, which is considered to be the main source of their particular properties, such as strongly enhanced diffusivities.