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Current Mirror Improved Potentiostat (CMIPot) for a Three Electrode Electrochemical Cell

机译:用于三电极电化学电池的电流镜改进型电化学仪 (CMIPot)

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摘要

This work presents a novel compact CMOS potentiostat-designed circuit for an electrochemical cell. The proposed topology functions as a circuit interface, controlling the polarization of voltage signals at the sensor electrodes and facilitating current measurement during the oxidation–reduction process of an analyzed solution. The potentiostat, designed for CMOS technology, comprises a two-stage amplifier, two current mirror blocks coupled to this amplifier, and a CMOS push–pull output stage. The electrochemical method of cyclic voltammetry is employed, operating within a voltage range of ±0.8 V and scan rates of 10 mV/s, 25 mV/s, 100 mV/s, and 250 mV/s. The circuit is capable of reading currents ranging from 10 µA to 500 µA. Experimental results were obtained using a potassium ferrocyanide K3[Fe(CN)6] redox solution with concentrations of 10, 15, and 20 mmol/L, and their corresponding voltammograms were evaluated. The experimental results from a discrete circuit demonstrate that the proposed potentiostat topology produces outcomes consistent with those of classical topologies presented in the literature and industrial equipment.
机译:这项工作提出了一种用于电化学电池的新型紧凑型 CMOS 恒电位仪设计的电路。所提出的拓扑结构用作电路接口,控制传感器电极上电压信号的极化,并促进分析溶液氧化还原过程中的电流测量。该恒电位仪专为 CMOS 技术而设计,包括一个两级放大器、两个耦合到该放大器的电流镜模块和一个 CMOS 推挽输出级。采用循环伏安法的电化学方法,在 ±0.8 V 的电压范围内工作,扫描速率为 10 mV/s、25 mV/s、100 mV/s 和 250 mV/s。该电路能够读取 10 μA 至 500 μA 的电流。使用浓度为 10、15 和 20 mmol/L 的亚铁氰化钾 K3[Fe(CN)6] 氧化还原溶液获得实验结果,并评估其相应的伏安图。分立电路的实验结果表明,所提出的恒电位仪拓扑产生的结果与文献和工业设备中提出的经典拓扑结构的结果一致。

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