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Valorization of Kraft Pulp and Paper Mill Slaker Grits and Biomass Fly Ash as Fillers in a Commercial Screed Mortar Formulation

机译:牛皮纸浆和造纸厂的 Slaker 砂砾和生物质粉煤灰作为商业砂浆配方中的填料

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摘要

Slaker grits (SG) and biomass fly ash (BFA), two waste streams generated in the pulp and paper industry, are commonly disposed of in landfills, a practice with a high economic and environmental burden. In this work, their individual valorization as fillers in a commercial screed mortar formulation was evaluated in order to achieve a more sustainable management practice. The waste streams were characterized in terms of true density, particle size and morphology, and chemical and mineralogical composition. The influence of their incorporation amount (5.0, 7.5, and 10.0 wt.% of the total solids) and pre-treatment (sieving and grinding) on the fresh (workability) and hardened state (density, water absorption by capillarity, and flexural and compressive strength) properties of the mortars were assessed. The results show that the addition of 10.0 wt.% of the SG after milling and sieving (<75 µm) and 7.5 wt.% of BFA in the as-received condition, or up to 10.0 wt.% after grinding and sieving (<63 µm), allowed for the production of mortar samples with properties within the recommended specifications and that were resistant to 25 consecutive freeze-thaw cycles. This waste valorization route could represent an economic benefit of up to 8.85 €/tmortar and 2.87 €/tmortar for mortar, and pulp and paper companies, respectively.
机译:Slaker 砂砾 (SG) 和生物质飞灰 (BFA) 是纸浆和造纸行业产生的两种废物流,通常被丢弃在垃圾填埋场,这种做法具有很高的经济和环境负担。在这项工作中,评估了它们在商用砂浆配方中作为填料的个体价值,以实现更可持续的管理实践。根据真实密度、粒径和形态以及化学和矿物成分对废物流进行表征。评估了它们的掺入量(占总固体的 5.0、7.5 和 10.0 wt.%)和预处理(筛分和研磨)对砂浆的新鲜(可加工性)和硬化状态(密度、毛细作用吸水率以及弯曲和抗压强度)性能的影响。结果表明,研磨和筛分后添加 10.0 wt.% 的 SG (<75 μm) 和 7.5 wt.% 的 BFA,或在研磨和筛分后添加高达 10.0 wt.% 的 BFA (<63 μm),可以生产出具有推荐规格性能的砂浆样品,并且能够抵抗 25 次连续冻融循环。对于砂浆、纸浆和造纸公司来说,这种废物估价路线可能分别代表高达 8.85 欧元/砂浆和 2.87 欧元/砂浆的经济利益。

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