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Amorphous Carbon Coatings for Total Knee Replacements—Part II: Tribological Behavior

机译:用于全膝关节替代的无定形碳涂料 - 第二部分:摩擦学行为

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摘要

Diamond-like carbon coatings may decrease implant wear, therefore, they are helping to reduce aseptic loosening and increase service life of total knee arthroplasties (TKAs). This two-part study addresses the development of such coatings for ultrahigh molecular weight polyethylene (UHMWPE) tibial inlays as well as cobalt-chromium-molybdenum (CoCr) and titanium (Ti64) alloy femoral components. While the deposition of a pure (a-C:H) and tungsten-doped hydrogen-containing amorphous carbon coating (a-C:H:W) as well as the detailed characterization of mechanical and adhesion properties were the subject of Part I, the tribological behavior is studied in Part II. Pin-on-disk tests are performed under artificial synovial fluid lubrication. Numerical elastohydrodynamic lubrication modeling is used to show the representability of contact conditions for TKAs and to assess the influence of coatings on lubrication conditions. The wear behavior is characterized by means of light and laser scanning microscopy, Raman spectroscopy, scanning electron microscopy and particle analyses. Although the coating leads to an increase in friction due to the considerably higher roughness, especially the UHMWPE wear is significantly reduced up to a factor of 49% (CoCr) and 77% (Ti64). Thereby, the coating shows continuous wear and no sudden failure or spallation of larger wear particles. This demonstrated the great potential of amorphous carbon coatings for knee replacements.
机译:钻石状碳涂层可能会降低植入物磨损,因此,它们有助于减少无菌松动和增加全膝关节育术(TKA)的使用寿命。这项两部分研究解决了超高分子量聚乙烯(UHMWPE)胫骨和钴 - 铬 - 钼(COCR)和钛(TI64)合金股骨组件的这种涂层的发展。虽然纯(Ac:h)和掺杂含氢的含氢的无定形碳涂料(Ac:h:w)的沉积以及机械和粘附性的详细表征是I部分的主题,但摩擦学行为是在第二部分研究。磁盘上的测试在人工滑膜液润滑下进行。数值弹性流体动力学润滑建模用于显示TKA的接触条件的可见性,并评估涂层对润滑条件的影响。磨损行为的特征在于光和激光扫描显微镜,拉曼光谱,扫描电子显微镜和颗粒分析。尽管涂层由于粗糙度显着增加而导致摩擦的增加,但特别是UHMWPE磨损显着降低至49%(COCR)和77%(TI64)。由此,涂层显示连续磨损,没有突然发生或较大磨损颗粒的脱模。这证明了无定形碳涂层用于膝关节置换的潜力。

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