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Surface Modification of Staple Carbon Fiber by Dopamine to Reinforce Natural Latex Composite

机译:多巴胺对短纤维碳纤维的表面改性以增强天然胶乳复合材料

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摘要

Carbon fiber significantly enhances the mechanical, thermal and electrical properties of rubber composites, which are widely used in aerospace, military, national defense and other cutting-edge fields. The preparation of a high-performance carbon fiber rubber composite has been a research hotspot, because the surface of carbon fiber is smooth, reactive inert and has a poor adhesion with rubber. In this paper, a high-performance rubber composite is prepared by mixing dopamine-modified staple carbon fiber with natural latex, and the mechanisms of modified carbon fiber-reinforced natural latex composite are explored. The experimental results show that the surface-modified staple carbon fiber forms uniform and widely covered polydopamine coatings, which significantly improve the interface adhesion between the carbon fiber and the rubber matrix. Meanwhile, when the concentration of dopamine is 1.5 g/L and the staple carbon fiber is modified for 6h, the carbon fiber rubber composite shows excellent conductivity, thermal conductivity, and dynamic mechanical properties, and its tensile strength is 10.6% higher than that of the unmodified sample.
机译:碳纤维显着增强了橡胶复合材料的机械,热和电性能,广泛用于航空航天,军事,国防和其他前沿领域。高性能碳纤维橡胶复合材料的制备一直是研究的热点,因为碳纤维表面光滑,反应性惰性且与橡胶的粘合性差。本文通过将多巴胺改性的人造短碳纤维与天然乳胶混合制备出高性能的橡胶复合材料,并探讨了改性碳纤维增强天然乳胶复合材料的机理。实验结果表明,经表面改性的人造短碳纤维形成均匀且覆盖广泛的聚多巴胺涂层,从而显着提高了碳纤维与橡胶基体之间的界面粘合力。同时,当多巴胺的浓度为1.5 g / L且对短纤维碳纤维进行改性6h时,该碳纤维橡胶复合材料显示出优异的导电性,导热性和动态力学性能,其抗张强度比其高10.6%。未经修改的样本。

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