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Special Issue: Advances in Homogeneous Catalysis

机译:特刊:均相催化的进展

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摘要

The use of enzymes, organo-catalysts or transition metal catalysts, as opposed to the employment of stoichiometric quantities of other traditional promoters of different organic synthetic processes (like, inorganic/organic bases, Brønsted acids, radicals, etc.) has allowed the discovery of a great number of new synthetic protocols within the toolbox of organic chemists. Moreover, the employment of the aforementioned catalysts in organic synthesis permits: ( ) the diminution of the global energy demand and production cost; ( ) the enhancement of both the chemoselectivity and stereoselectivity of the global process; and ( ) the reduction of metal-, organo- or bio-catalyst consumption, thanks to the possible recycling of the catalysts; all these being synthetic concepts closely related with the principles of so-called Thus, this Special Issue on “ ” has been aimed to showcase a series of stimulating contributions from international experts within different sub-areas of catalysis in organic synthesis (ranging from metal-, organo-, or bio-catalyzed organic reactions).
机译:与使用化学计量的不同有机合成过程的其他传统促进剂(例如无机/有机碱,布朗斯台德酸,自由基等)相反,使用酶,有机催化剂或过渡金属催化剂使发现成为可能有机化学家工具箱中的大量新合成方案。此外,上述催化剂在有机合成中的使用允许:()全球能源需求和生产成本的减少; ()增强全局过程的化学选择性和立体选择性; ()由于可以回收催化剂,减少了金属,有机或生物催化剂的消耗;所有这些都是与所谓原理密切相关的合成概念。因此,本期“”专刊旨在展示国际专家在有机合成催化不同子领域(从金属,有机或生物催化的有机反应)。

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