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Interference of surface plasmon resonances causes enhanced depolarized light scattering from metal nanoparticles

机译:表面等离子体激元共振的干扰导致金属纳米颗粒的去偏振光散射增强

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摘要

We show that the strongly depolarized light scattering from noble metal particles is a result of interference of two surface plasmon resonances on the same particle. The maximum depolarization occurs between two resonances. Under favorable conditions the anisotropy of the scattering light can be much lower than what is possible for dielectric particles. This explanation is discussed in relation to earlier published experimental measurements. Comparison of experimental results with theoretical calculations provides information on the shape distribution of metallic particles in the suspension.
机译:我们表明,贵金属颗粒的强烈去偏振光散射是同一颗粒上两个表面等离子体共振的干扰的结果。最大的去极化发生在两个共振之间。在有利的条件下,散射光的各向异性可能比介电颗粒可能的各向异性低得多。关于较早出版的实验测量讨论了该解释。实验结果与理论计算的比较提供了有关悬浮液中金属颗粒形状分布的信息。

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