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Formalism for Hypercomplex Multidimensional NMR Employing Partial-Component Subsampling

机译:采用部分组件的超细复用多维NMR的形式主义

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摘要

Multidimensional NMR spectroscopy typically employs phase-sensitive detection, which results in hypercomplex data (and spectra) when utilized in more than one dimension. Nonuniform sampling approaches have become commonplace in multidimensional NMR, enabling dramatic reductions in experiment time, increases in sensitivity and/or increases in resolution. In order to utilize nonuniform sampling optimally, it is necessary to characterize the relationship between the spectrum of a uniformly sampled data set and the spectrum of a subsampled data set. In this work we construct an algebra of hypercomplex numbers suitable for representing multidimensional NMR data along with partial-component nonuniform sampling (i.e. the hypercomplex components of data points are subsampled). This formalism leads to a modified DFT–convolution relationship involving a partial-component, hypercomplex point-spread function set. The framework presented here is essential for the continued development and appropriate characterization of partial-component nonuniform sampling.
机译:多维NMR光谱通常采用相敏检测,在多于一维使用时会导致超复杂数据(和光谱)。非均匀采样方法已在多维NMR中变得司空见惯,从而可以大大减少实验时间,提高灵敏度和/或提高分辨率。为了最佳地利用非均匀采样,必须表征均匀采样的数据集的频谱与子采样的数据集的频谱之间的关系。在这项工作中,我们构建了适合表示多维NMR数据以及部分分量非均匀采样(即数据点的超复杂分量被二次采样)的超复数代数。这种形式主义导致了修改后的DFT-卷积关系,涉及部分分量,超复杂点扩展函数集。此处介绍的框架对于继续开发和适当表征部分分量非均匀采样至关重要。

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