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Preparation of Few-Layer Bismuth Selenide by Liquid-Phase-Exfoliation and Its Optical Absorption Properties

机译:液相剥脱法制备多层硒化铋及其光吸收性能

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摘要

Bismuth selenide (Bi2Se3), a new topological insulator, has attracted much attention in recent years owing to its relatively simple band structure and large bulk band gap. Compared to bulk, few-layer Bi2Se3 is recently considered as a highly promising material. Here, we use a liquid-phase exfoliation method to prepare few-layer Bi2Se3 in N-methyl-2-pyrrolidone or chitosan acetic solution. The resulted few-layer Bi2Se3 dispersion demonstrates an interesting absorption in the visible light region, which is different from bulk Bi2Se3 without any absorption in this region. The absorption spectrum of few-layer Bi2Se3 depends on its size and layer number. At the same time, the nonlinear and saturable absorption of few-layer Bi2Se3 thin film in near infrared is also characterized well and further exploited to generate laser pulses by a passive Q-switching technique. Stable Q-switched operation is achieved with a lower pump threshold of 9.3 mW at 974 nm, pulse energy of 39.8 nJ and a wide range of pulse-repetition-rate from 6.2 to 40.1 kHz. Therefore, the few-layer Bi2Se3 may excite a potential applications in laser photonics and optoelectronic devices.
机译:硒化铋(Bi2Se3)是一种新型的拓扑绝缘体,近年来由于其带结构相对简单且体带隙较大而备受关注。与块状相比,最近几层Bi2Se3被认为是一种很有前途的材料。在这里,我们使用液相剥离法在N-甲基-2-吡咯烷酮或壳聚糖乙酸溶液中制备几层Bi2Se3。所得的几层Bi2Se3分散体在可见光区域显示出有趣的吸收,这与本体Bi2Se3在该区域中没有任何吸收的情况不同。双层Bi2Se3的吸收光谱取决于其大小和层数。同时,还很好地表征了几层Bi2Se3薄膜在近红外中的非线性饱和吸收,并通过无源Q开关技术进一步开发了其产生激光脉冲的方法。在974 nm处有9.3 pumpmW的较低泵浦阈值,39.8 nJ的脉冲能量和6.2至40.1 kHz的宽脉冲重复率范围,可实现稳定的Q开关操作。因此,很少层的Bi2Se3可能会激发激光光子学和光电器件中的潜在应用。

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