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Syringeless Electrospinning toward Versatile Fabrication of Nanofiber Web

机译:针刺静电纺向纳米纤维网的多功能制造

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摘要

Although electrospinning is considered a powerful and generic tool for the preparation of nanofiber webs, several issues still need to be overcome for real-world applications. Most of these issues stem from the use of a syringe-based system, where the key factor influencing successful electrospinning is the maintenance of several subtle balances such as those of between the mass and the electrical state. It is extremely difficult to maintain these balances throughout the spinning process until all the polymeric solution in the syringe has been consumed. To overcome these limitations, we have developed a syringeless electrospinning technique as an alternative and efficient means of preparing a nanofiber web. This new technique uses a helically probed rotating cylinder. This technique can not only cover conventional methods, but also provides several advantages over syringe-based and needless electrospinning in terms of productivity (6 times higher) and processibility. For example, we can produce nanofibers with highly crystalline polymers and nanofiber-webs comprising networks of several different polymers, which is sometimes difficult in conventional electrospinning. In addition, this method provides several benefits for colloidal electrospinning as well. This method should help expand the range of applications for electrospun nanofiber webs in the near future.
机译:尽管静电纺丝被认为是制备纳米纤维网的强大而通用的工具,但对于实际应用而言仍需要克服一些问题。这些问题大多数来自使用基于注射器的系统,其中影响成功静电纺丝的关键因素是维持一些微妙的平衡,例如质量与电态之间的平衡。在注射器中所有的聚合物溶液都消耗完之前,要在整个纺丝过程中保持这些平衡非常困难。为了克服这些局限性,我们开发了无注射器静电纺丝技术,作为制备纳米纤维网的另一种有效途径。这项新技术使用了一个螺旋探测的旋转圆柱体。该技术不仅可以覆盖传统方法,而且在生产率(高6倍)和可加工性方面,比基于注射器的和不必要的静电纺丝具有多个优势。例如,我们可以生产具有高结晶度聚合物的纳米纤维,以及包含几种不同聚合物网络的纳米纤维网,这在常规电纺中有时会很困难。另外,该方法也为胶体静电纺丝提供了许多益处。这种方法应有助于在不久的将来扩大静电纺纳米纤维网的应用范围。

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