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Spontaneous emergence of chirality in achiral lyotropic chromonic liquid crystals confined to cylinders

机译:局限于圆柱体的非手性溶致色团液晶中手性的自发出现

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摘要

The presumed ground state of a nematic fluid confined in a cylindrical geometry with planar anchoring corresponds to that of an axial configuration, wherein the director, free of deformations, is along the long axis of the cylinder. However, upon confinement of lyotropic chromonic liquid crystals in cylindrical geometries, here we uncover a surprising ground state corresponding to a doubly twisted director configuration. The stability of this ground state, which involves significant director deformations, can be rationalized by the saddle-splay contribution to the free energy. We show that sufficient anisotropy in the elastic constants drives the transition from a deformation-free ground state to a doubly twisted structure, and results in spontaneous symmetry breaking with equal probability for either handedness. Enabled by the twist angle measurements of the spontaneous twist, we determine the saddle-splay elastic constant for chromonic liquid crystals for the first time.
机译:限制为具有平面锚固的圆柱形几何形状的向列流体的假定基态对应于轴向构造的基态,其中指向矢没有变形,沿着圆柱体的长轴。但是,在将溶致色性液晶限制在圆柱几何形状后,在这里我们发现了与双扭曲指向矢构型相对应的令人惊讶的基态。该基态的稳定性(包括明显的指向矢变形)可以通过对自由能的鞍形展开贡献来合理化。我们表明,弹性常数中的足够各向异性驱动了从无变形的基态到双扭曲结构的过渡,并导致自发对称性破裂,而任何一种惯性都具有相同的概率。通过测量自发扭曲的扭曲角,我们首次确定了发色液晶的鞍形展开弹性常数。

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