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Determination and analysis of harmful components in synthetic running tracks from Chinese primary and middle schools

机译:中国中小学合成滑道中有害成分的测定与分析

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摘要

In China, incidences involving pupils suffering health problems caused by synthetic running tracks have attracted the public’s attention. However, the existence of known and unknown harmful chemicals in the tracks have not yet been explored. Here, the levels of 16 known harmful ingredients were firstly analyzed in 167 school running tracks. In all samples, the recognized toxic solvents and additives, such as the benzene series, soluble mercury, 3,3′-dichloro-4,4′-diaminodiphenylmethane (MOCA) and toluene diisocyanate monomer (TDI) were under the limits of detection. In contrast, polycyclic aromatic hydrocarbons (PAHs), phthalates, Short chain chlorinated paraffins (SCCPs) soluble lead, cadmium and chromium were found in 86%, 88%, 46%, 81%, 43% and 83% of the specimens, respectively. The levels, toxicology and distribution of these known chemicals were evaluated. Then, a static-headspace gas chromatography-mass spectrometer (GC-MS) method in full scan mode was employed to screen for unknown volatile chemicals. Three groups of chemicals reflecting different kinds of pollution sources were discovered: new solvents, such as N, N-Dimethylformamide, new additives, such as 2-ethylhexanoic acid, and by-products, such as carbon disulfide. In summary, the existence of potential risk factors in school plastic tracks was revealed through exhaustive testing. Moreover, most of the hazardous components detected have been recently included in a new national standard to improve the safety performance of synthetic running tracks.
机译:在中国,由合成跑道引起的学生健康问题的发生引起了公众的关注。但是,尚未探索轨道中已知和未知有害化学物质的存在。在这里,首先在167条学校跑道上分析了16种已知有害成分的含量。在所有样品中,公认的有毒溶剂和添加剂,例如苯系列,可溶性汞,3,3'-二氯-4,4'-二氨基二苯甲烷(MOCA)和甲苯二异氰酸酯单体(TDI)都在检测范围内。相比之下,样品中的多环芳烃(PAHs),邻苯二甲酸盐,短链氯化石蜡(SCCPs)可溶性铅,镉和铬的含量分别为86%,88%,46%,81%,43%和83%。 。对这些已知化学物质的水平,毒理学和分布进行了评估。然后,采用全扫描模式的静态顶空气相色谱-质谱仪(GC-MS)方法来筛选未知的挥发性化学物质。发现了三类反映不同污染源的化学物质:新溶剂(例如N,N-二甲基甲酰胺),新添加剂(例如2-乙基己酸)和副产物(例如二硫化碳)。总之,通过详尽的测试揭示了学校塑胶跑道中潜在的危险因素的存在。此外,最近检测到的大多数危险成分已被纳入新的国家标准中,以改善合成跑道的安全性能。

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