Di-μ-azido-κ4N:N-bis­({2-(3-amino-22-dimethyl­prop­yl)imino­meth­yl-6-meth­oxy­phenolato-1κ3NN′O1}copper(II))

摘要

The complete mol­ecule of the title complex, [Cu2(C13H19N2O2)2(N3)2], is generated by the application of a centre of inversion. The central Cu2N2 core is a rhombus as the μ2-azide ligands bridge in an asymmetric fashion. Each Cu^II atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anti­cipated oxide O, imine N and amine N atoms. The resulting N4O coordination geometry is based on a square pyramid. No specific inter­molecular inter­actions are noted in the crystal packing, but the amine H atoms form intra­molecular N—H⋯O(oxide)/N(azide) hydrogen bonds.