In the crystal of the title polymeric compound, [CdBr2(C12H12N2)]n, the CdII cation is located on a twofold rotation axis and is six-coordinated in a distorted octahedral geometry formed by two N atoms from the 4,4′-dimethyl-2,2′-bipyridine ligand and by four bridging Br− anions. The bridging function of the Br− anions leads to a polymeric chain running along the c axis. Weak C—H⋯π interactions observed between adjacent chains are effective in the stabilization of the three-dimensional packing.
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机译:在标题聚合物[CdBr2(C12H12N2)] n的晶体中,Cd II sup>阳离子位于两倍旋转轴上,并在由两个N原子形成的扭曲八面体几何形状中六配位由4,4'-二甲基-2,2'-联吡啶配体和四个桥接的Br - sup>阴离子形成。 Br - sup>阴离子的桥连功能导致聚合物链沿c轴延伸。在相邻链之间观察到的弱CH-H⋯π相互作用对稳定三维堆积有效。
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