首页> 美国卫生研究院文献>Acta Crystallographica Section E: Crystallographic Communications >5-n-Butyl-4-2-(2-ethyl-1-benzothio­phen-3-yl)-334455-hexa­fluoro­cyclo­pent-1-en-1-ylthio­phene-2-carbaldehyde
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5-n-Butyl-4-2-(2-ethyl-1-benzothio­phen-3-yl)-334455-hexa­fluoro­cyclo­pent-1-en-1-ylthio­phene-2-carbaldehyde

机译:5-正丁基-4- 2-(2-乙基-2-苯并噻吩-3-基)-334455-六氟环戊-1-烯-1-基噻吩-2甲醛

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摘要

The title compound, C24H20F6OS2, exhibiting photochromic behaviour, has thienyl and benzothienyl substituents attached to the double-bond C atoms of the envelope-shaped cyclo­pentene ring. The mean planes of aromatic systems form dihedral angles of 43.0 (1) (thien­yl) and 73.8 (1)° (benzothien­yl) with the mean plane of the C—C=C—C portion of the cyclo­pentene ring. This conformation avoids steric hindrance between the n-butyl and ethyl substituents. The formyl substituent of the thienyl group, as well as the ethyl substituent of the benzothienyl group, are disordered [occupancies of 0.788 (17):0.212 (17) and 0.64 (5):0.36 (5), respectively].
机译:标题化合物C24H20F6OS2具有光致变色特性,其噻吩基和苯并噻吩基取代基连接到信封形环戊烯环的双键C原子上。芳族体系的平均平面与环­戊烯环的CC = CC部分的平均平面形成43.0(1)(噻吩基)和73.8(1)°(苯并噻吩基)的二面角。这种构象避免了正丁基和乙基取代基之间的空间位阻。噻吩基的甲酰基取代基和苯并噻吩基的乙基取代基是无序的[占有率分别为0.788(17):0.212(17)和0.64(5):0.36(5)]。

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