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Novel pyridine-based Pd(II)-complex for efficient Suzuki coupling of aryl halides under microwaves irradiation in water

机译：新型吡啶基Pd（II）-络合物用于水中微波辐射下芳基卤化物的有效Suzuki偶联

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摘要

Suzuki C–C cross-coupling of aryl halides with aryl boronic acids using new phosphene-free palladium complexes as precatalysts was investigated. A pyridine-based Pd(II)-complex was used in open air under thermal as well as microwave irradiation conditions using water as an eco-friendly green solvent.

机译：使用新型无磷钯配合物作为前催化剂，对芳基卤化物与芳基硼酸的Suzuki C–C交叉偶联进行了研究。基于吡啶的Pd（II）配合物在露天和热辐射以及微波辐射条件下使用水作为环保绿色溶剂使用。

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期刊名称 BMC Chemistry
作者
Ismail I. Althagafi; Mohamed R. Shaaban; Aisha Y. Al-dawood; Ahmad M. Farag;
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作者单位

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年(卷),期 2017(11),-1
年度 2017
页码 88
总页数 9
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
关键词
Palladium precatalyst Suzuki–Miyaura C–C cross-coupling Microwave irradiation;

机译：钯预催化剂;铃木宫浦;CC交叉偶联;微波辐射;

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专利

1. Novel pyridine-based Pd(II)-complex for efficient Suzuki coupling of aryl halides under microwaves irradiation in water [J] . Ismail I. Althagafi, Mohamed R. Shaaban, Aisha Y. Al-dawood, Chemistry central journal . 2017,第1期

机译：新型吡啶基Pd（II）-配合物，用于水中微波辐射下芳基卤化物的有效Suzuki偶联
2. Nanosilica-anchored Pd(II)-Schiff base complex as efficient heterogeneous catalyst for activation of aryl halides in Suzuki-Miyaura cross-coupling reaction in water [J] . Gogoi Nibedita, Bora Utpal, Borah Geetika, Applied Organometallic Chemistry . 2017,第9期

机译：纳米硅基锚定Pd（II） - 作为活化芳基卤化物在水中铃木卤化物激活的高效异质催化剂
3. Picolinamide modified β-cyclodextrin/Pd (II) complex: Asupramolecular catalyst for Suzuki-Miyaura coupling of aryl, benzyl and allyl halides with arylboronic acids in water [J] . Kaixiu Luo, Lu Zhang, Rui Yang, Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides . 2018,第期

机译：吡啶胺酰胺改性β-环糊精/ Pd（II）复合物：用于芳基，苄基和烯丙基卤化物与水中芳基苯酸的芳基，苄基和烯丙基卤化物的Asupramulary催化剂
4. Micro-reactor synthesis: synthesis of cyanobiphenyls using a modified suzuki coupling of an aryl halide and aryl boronic acid. [C] . Victoria Skelton, Gillian M.Greenway, Stephen J.Haswell, International conference on microreaction technology . 2000

机译：微反应器合成：使用芳基卤化物和芳族硼酸的改性铃木偶联来合成氰基苯基。
5. Part I: Microwave-Assisted Continuous Flow Organic Synthesis (MACOS) and the Heck-type aminocarbonylation of aryl halides, and, the Suzuki-Miyaura cross-coupling of chloroformates. Part II: Structure-activity relationship (SAR) analysis of NHC-palladium PEPPSI complexes in aminations and cross-couplings [D] . Nasielski, Joanna 2009

机译：第一部分：微波辅助连续流动有机合成（MACOS）和芳基卤化物的Heck型氨基羰基化，以及氯甲酸酯的Suzuki-Miyaura交叉偶联。第二部分：胺和交叉偶联中NHC-钯PEPPSI复合物的结构-活性关系（SAR）分析
6. A novel 4-aminoantipyrine-Pd(II) complex catalyzes Suzuki–Miyaura cross-coupling reactions of aryl halides [O] . Claudia Araceli Contreras-Celedón, Darío Mendoza-Rayo, José A Rincón-Medina, 2014

机译：新型的4-氨基安替比林-Pd（II）配合物催化芳基卤化物的Suzuki-Miyaura交叉偶联反应
7. A novel 4-aminoantipyrine-Pd(II) complex catalyzes Suzuki–Miyaura cross-coupling reactions of aryl halides [O] . Claudia A. Contreras-Celedón, Darío Mendoza-Rayo, José A. Rincón-Medina, 2014

机译：一种新型4-氨基安替比林-pd（II）配合物催化芳基卤化物的suzuki-miyaura交叉偶联反应

Novel pyridine-based Pd(II)-complex for efficient Suzuki coupling of aryl halides under microwaves irradiation in water

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