Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(26-diisopropyl­phenyl­amido-κN)zirconium(IV)

摘要

In the title compound, [Zr(C12H18N)2(C4H10N)2(C4H11N)] or [Zr(HNC6H3 ⁱPr2)2(NEt2)2(HNEt2)], which was obtained by the reaction of Zr(NEt)4 with ⁱPr₂C₆H₃NH₂, the Zr^IV atom is in a trigonal–bipiramidal geometry in which the N atoms from two ⁱPr₂C₆H₃NH and one NEt₂ ligand occupy the equatorial positions, and the N atoms of an NEt₂ and an Et₂NH ligand occupy the apical positions. An intra­molecular N—H⋯N contact occurs. There are two independent molecules in the asymmetric unit.