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Recent Advances on Metal-Free Visible-Light- Induced Catalysis for Assembling Nitrogen- and Oxygen-Based Heterocyclic Scaffolds

机译:无金属可见光诱导的用于组装基于氮和氧的杂环支架的最新进展

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摘要

Heterocycles are important class of structures, which occupy a major space in the domain of natural and bioactive compounds. For this reason, development of new synthetic strategies for their controllable synthesis became of special interests. The development of novel photoredox systems with wide-range application in organic synthesis is particularly interesting. Organic dyes have been widely applied as photoredox catalysts in organic synthesis. Their low costs compared to the typical photocatalysts based on transition metals make them an excellent alternative. This review describes proceedings since 2015 in the area of application of metal-free, visible-light-mediated catalysis for assembling various heterocyclic scaffolds containing five- and six-membered rings bearing nitrogen and oxygen heteroatoms.
机译:杂环是重要的结构类别,其在天然和生物活性化合物的领域中占据主要空间。因此,针对其可控合成的新合成策略的开发变得特别有意义。在有机合成中具有广泛应用的新型光氧化还原系统的开发特别有趣。有机染料已广泛用作有机合成中的光氧化还原催化剂。与基于过渡金属的典型光催化剂相比,它们的成本低,使其成为绝佳的替代品。这篇综述描述了自2015年以来在无金属,可见光介导的催化领域的应用程序,该过程用于组装各种含有5个和6个带有氮和氧杂原子的环的杂环支架。

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