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Biogenic Synthesis of Cu-Doped ZnO Photocatalyst for the Removal of Organic Dye

机译:Cu 掺杂 ZnO 光催化剂的生物合成用于去除有机染料

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摘要

The Cu-doped ZnO photocatalysts were prepared with a green and coprecipitation approach by using water hyacinth (Eichhornia crassipes) aquatic plant extract. In the preparation process, different amount of copper precursors such as 1, 2, 3, 4, and 5% of molar ratio were added to zinc nitrate precursors and abbreviated as Cu-ZnO (1%), Cu-ZnO (2%), Cu-ZnO (3%), Cu-ZnO (4%), and Cu-ZnO (5%), respectively. The characterization of the obtained samples was carried out, and the removal of the methylene blue (MB) dye was examined. Out of all catalysts, Cu-ZnO (3%) had the best photocatalytic performance and 89% of the MB dye was degraded. However, the degradation performances of blank (without catalysts), ZnO, Cu-ZnO (1%), Cu-ZnO (2%), Cu-ZnO (4%), and Cu-ZnO (5%) catalysts were 6, 54, 69, 83, 80, and 73%, respectively. Therefore, the use of water hyacinth plant extract with the optimum amount of Cu added to ZnO during the preparation of the catalyst could have a promising application in the degradation of organic pollutants.
机译:使用水葫芦 (Eichhornia crassipes) 水生植物提取物,采用绿色共沉淀方法制备了 Cu 掺杂的 ZnO 光催化剂。在制备过程中,在硝酸锌前驱体中加入摩尔比的 1、2、3、4 和 5% 等不同量的铜前驱体,分别缩写为 Cu-ZnO (1%)、Cu-ZnO (2%)、Cu-ZnO (3%)、Cu-ZnO (4%) 和 Cu-ZnO (5%)。对获得的样品进行表征,并检查亚甲蓝 (MB) 染料的去除情况。在所有催化剂中,Cu-ZnO (3%) 具有最好的光催化性能,89% 的 MB 染料被降解。然而,空白(无催化剂)、ZnO、Cu-ZnO (1%)、Cu-ZnO (2%)、Cu-ZnO (4%) 和 Cu-ZnO (5%) 催化剂的降解性能分别为 6、54、69、83、80 和 73%。因此,在催化剂制备过程中使用水葫芦植物提取物并在 ZnO 中添加最佳量的 Cu 可能在有机污染物的降解中具有广阔的应用前景。

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