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Enhancing the Quality of Polypropylene Recyclates: Predictive Modelling of the Melt Flow Rate and Shear Viscosity

机译:提高聚丙烯回收物的质量:熔体流动速率和剪切粘度的预测建模

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摘要

The extensive use of polypropylene (PP) in various industries has heightened interest in developing efficient methods for recycling and optimising its mixtures. This study focuses on formulating predictive models for the Melt Flow Rate (MFR) and shear viscosity of PP blends. The investigation involved characterising various grades, including virgin homopolymers, copolymers, and post-consumer recyclates, in accordance with ISO 1133 standards. The research examined both binary and ternary blends, utilising traditional mixing rules and symbolic regression to predict rheological properties. High accuracy was achieved with the Arrhenius and Cragoe models, attaining R2 values over 0.99. Symbolic regression further enhanced these models, offering significant improvements. To mitigate overfitting, empirical noise and variable swapping were introduced, increasing the models’ robustness and generalisability. The results demonstrated that the developed models could reliably predict MFR and shear viscosity, providing a valuable tool for improving the quality and consistency of PP mixtures. These advancements support the development of recycling technologies and sustainable practices in the polymer industry by optimising processing and enhancing the use of recycled materials.
机译:聚丙烯 (PP) 在各个行业中的广泛使用提高了人们对开发有效回收和优化其混合物的方法的兴趣。本研究的重点是为 PP 共混物的熔体流动速率 (MFR) 和剪切粘度制定预测模型。该调查涉及根据 ISO 1133 标准对各种等级的表征,包括原生均聚物、共聚物和消费后回收物。该研究检查了二元和三元共混物,利用传统的混合规则和符号回归来预测流变特性。Arrhenius 和 Cragoe 模型实现了高精度,R2 值超过 0.99。符号回归进一步增强了这些模型,提供了显著的改进。为了减少过拟合,引入了经验噪声和变量交换,从而提高了模型的稳健性和泛化性。结果表明,开发的模型可以可靠地预测 MFR 和剪切粘度,为提高 PP 混合物的质量和一致性提供了有价值的工具。这些进步通过优化加工和加强回收材料的使用,支持聚合物行业回收技术和可持续实践的发展。

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