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Modeling Approach for Reactive Injection Molding of Polydisperse Suspensions with Recycled Thermoset Composites

机译:使用回收热固性复合材料对多分散悬浮液进行反应注射成型的建模方法

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摘要

Recycling production waste in the reactive injection molding (RIM) process is a step towards sustainability and efficient material usage. The recycled thermoset composite (RTC) material obtained by shredding the production waste is reused with a virgin thermoset composite (VTC). This study presents a mold-filling simulation approach considering this polydisperse suspension of RTC and VTC. Mold-filling simulations can assist in predicting processability and assessing the impact of reinforced RTC on the final part of production. State-of-the-art mold-filling simulations use the Cross–Castro–Macosko (CCM) model or anisotropic fiber-orientation-dependent viscosity models. The rheological parameters are determined either for the VTC or neat resin. However, these models do not account for changes in viscosity due to the reinforcing of fillers such as RTC. An effective viscosity model is developed by extending the CCM model using the stress–strain amplification approach to overcome this gap. This model is implemented in the computational fluid dynamics code OpenFOAM, and simulations are performed using an extended multiphase solver. To validate the simulations, experimental trials were executed using a two-cavity mold equipped with pressure sensors. Molding compounds with different compositions of VTC and RTC were injected at different speeds. Reinforcing VTC with RTC increases the viscosity. Results demonstrate that RTC-reinforced compounds require higher injection pressure for mold filling than VTC alone. The qualitative agreement of pressure profiles from simulations and experiments for different proportions of reinforcing RTC and different injection speeds shows that the implemented viscosity model can reproduce the experimental mold-filling behavior.
机译:在反应注塑成型 (RIM) 工艺中回收生产废料是迈向可持续性和高效材料利用的一步。通过切碎生产废料获得的回收热固性复合材料 (RTC) 材料与原始热固性复合材料 (VTC) 一起重新利用。本研究提出了一种考虑 RTC 和 VTC 的多分散悬浮液的模具填充模拟方法。模具填充模拟有助于预测可加工性并评估增强 RTC 对生产最终部分的影响。最先进的模具填充模拟使用 Cross-Castro-Macosko (CCM) 模型或各向异性纤维取向相关粘度模型。流变参数是针对 VTC 或纯树脂确定的。然而,这些模型没有考虑由于 RTC 等填料的增强而导致的粘度变化。通过使用应力-应变放大方法扩展 CCM 模型来克服这一差距,从而开发了一个有效的粘度模型。该模型在计算流体动力学代码 OpenFOAM 中实现,并使用扩展的多相求解器进行仿真。为了验证模拟,使用配备压力传感器的双腔模具进行了实验试验。具有不同 VTC 和 RTC 成分的模塑料以不同的速度注入。用 RTC 增强 VTC 会增加粘度。结果表明,与单独的 VTC 相比,RTC 增强化合物需要更高的注射压力来填充模具。来自不同增强 RTC 比例和不同注射速度的模拟和实验压力曲线的定性一致性表明,实现的粘度模型可以再现实验性的模具填充行为。

著录项

  • 期刊名称 Polymers
  • 作者单位
  • 年(卷),期 2024(16),16
  • 年度 2024
  • 页码 2245
  • 总页数 19
  • 原文格式 PDF
  • 正文语种
  • 中图分类 分子生物学;
  • 关键词

    机译:反应性注塑成型;高填充热固性悬浮液;回收热固性复合材料;多相流;OpenFOAM;
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