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Lifetime and Molecular Coupling in Surface Phonon Polariton Resonators

机译:表面声子极化激元谐振器中的寿命和分子耦合

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摘要

Surface phonon polariton (SPhP) modes in polar semiconductors offer a low-loss platform for infrared nanophotonics and sensing. However, the efficient design of polariton-enhanced sensors requires a quantitative understanding of how to engineer the frequency and lifetime of SPhPs in nanophotonic structures. Here, we study organ-pipe resonances in 4H-SiC trenches as a prototype system for infrared sensing. We use a transmission line framework that accounts for the field distribution within the trench, accurately predicting mode frequency and lifetime when compared against finite element method (FEM) electromagnetic calculations. Accounting for the electric field profile across the gap is critical in our model to accurately predict mode frequencies, quality factor (Q factor), and reflectance, outperforming previous circuit models developed in the literature. Beyond structural simulation, our model can provide insights into the frequency ranges in the Reststrahlen band where enhanced sensor activity should be present. The radiative lifetime is significantly enlarged close to the longitudinal optic phonon, restricting sensor efficiency at this wavelength range. This pushes the optimal frequency for sensing closer to the center of the Reststrahlen band than might be naively expected. This model ultimately demonstrates the primary challenge of designing SPhP-based sensors: only a relatively narrow region of the Reststrahlen band offers efficient sensing, guiding future designs for infrared spectroscopy.
机译:极性半导体中的表面声子极化激元 (SPhP) 模式为红外纳米光子学和传感提供了一个低损耗平台。然而,极化激元增强传感器的高效设计需要定量了解如何在纳米光子结构中设计 SPhP 的频率和寿命。在这里,我们研究了 4H-SiC 沟槽中的风琴管共振,作为红外传感的原型系统。我们使用一个传输线框架来考虑沟槽内的场分布,与有限元法 (FEM) 电磁计算相比,可以准确预测模式频率和寿命。在我们的模型中,考虑间隙上的电场分布对于准确预测模式频率、品质因数(Q 因子)和反射率至关重要,其性能优于文献中开发的先前电路模型。除了结构仿真之外,我们的模型还可以深入了解 Reststrahlen 频段的频率范围,其中应该存在增强的传感器活动。辐射寿命在接近纵向光声子时显著延长,限制了该波长范围内的传感器效率。这使得感应的最佳频率比天真预期的更接近 Reststrahlen 波段的中心。该模型最终展示了设计基于 SPhP 的传感器的主要挑战:只有 Reststrahlen 波段相对狭窄的区域才能提供有效的传感,指导未来的红外光谱设计。

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