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Effect of Micro-Scale Er on the Microstructure and Fluidity of ZL205A Alloy

机译:微量Er对ZL205A合金组织和流动性的影响。

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摘要

The effect of Er addition on the fluidity and microstructure transformation of the as-cast and T5 heat-treated ZL205A alloys was investigated by optical microscope (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectrometer (EDS). The fluidity of the liquid metal after adding Er was tested and the fracture characteristics of the material were analyzed. The results indicated that Er was mainly dissolved into an α–Al matrix near the grain boundaries (GBs). It is easily segregated and enriched in the intersection of the GBs or the interface between the α and θ phase, which caused the intermetallic compounds to be distributed along the GBs to the neck and to fuse. Er could also inhibit the diffusion of Cu atoms in the process of solid solution, so that increased the residual eutectic structures in the crystal, while accelerating the precipitation progress of the Guinier–Preston (GP) zone and θ’ phase and increasing precipitation of the θ phase. A small amount of precipitation of θ phase and micro-scale Er (0.1–0.5 wt %) can significantly increase the fluidity and reduce the casting defects, which can effectively improve the castability of the ZL205A alloy. The interface between the (Al8Cu4Er) phase and matrix is the main area of microcracks, through analyzing the fracture morphology.
机译:通过光学显微镜(OM),扫描电子显微镜(SEM),X射线衍射(XRD)和能谱仪研究了添加Er对铸态和T5热处理的ZL205A合金的流动性和组织转变的影响。 (EDS)。测试了添加Er后液态金属的流动性,并分析了材料的断裂特性。结果表明,Er主要溶解在晶界(GBs)附近的α-Al基体中。它很容易在GBs的相交处或α相与θ相之间的界面处分离和富集,这导致金属间化合物沿GBs分布到颈部并融合。 Er还可以抑制固溶过程中Cu原子的扩散,从而增加了晶体中的残留共晶结构,同时加快了Guinier-Preston(GP)区和θ'相的沉淀过程,并增加了Cu'er相的沉淀。 θ相。少量的θ相和微量Er(0.1-0.5 wt%)的析出可以显着增加流动性并减少铸造缺陷,从而可以有效地改善ZL205A合金的铸造性。通过分析断裂形态,(Al8Cu4Er)相与基体之间的界面是微裂纹的主要区域。

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