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Hot Corrosion Behavior of Sputtered Nanocrystalline Coating with Yttrium Addition at 900 °C

机译:900℃下添加钇的溅射纳米晶涂层的热腐蚀行为

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摘要

The high temperature corrosion behavior of sputtered nanocrystalline K38 coating with and without yttrium addition under mixed molten salt film in air was investigated. Accelerated corrosion occurred on the coating without yttrium (Y) addition locally after 60 h exposure at 900°C, which resulted in negative weight gain in kinetics. A uniform and protective alumina scale formed on surface of the coating containing yttrium in comparison. Y enriched particle as corrosion product was observed on the top of alumina scale. The results indicated the beneficial influence of Y on the chemical stability of the protective scale in the presence of chloride. The mechanism was discussed.
机译:研究了在空气中混合熔融盐膜下添加和不添加钇的溅射纳米晶K38涂层的高温腐蚀行为。在900°C下暴露60 h后,局部未添加钇(Y)的涂层发生了加速腐蚀,这导致动力学上的负重增加。相比之下,在含有钇的涂层表面上形成了均匀且保护性的氧化铝水垢。在氧化铝鳞片的顶部观察到富集的Y颗粒作为腐蚀产物。结果表明,在氯化物存在下,Y对防护垢化学稳定性的有益影响。讨论了该机制。

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