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From Jackfruit Rags to Hierarchical Porous N-Doped Carbon:A High-Performance Anode Material for Sodium-Ion Batteries

机译:从菠萝蜜碎布到多孔多孔N掺杂碳:一种用于钠离子电池的高性能阳极材料

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摘要

Renewable biomass-derived carbon materials have attracted increasing research attention as promising electrode materials for electrochemical energy storage devices,such as sodium-ion batteries (SIBs),due to their outstanding electrical conductivity,hierarchical porous structure,intrinsic heteroatom doping,and environmental friendliness.Here,we investigate the potential of hierarchical N-doped porous carbon (NPC) derived from jackfruit rags through a facile pyrolysis as an anode material for SIBs.The cycling performance of NPC at 1 A/g for 2000 cycles featured a stable reversible capacity of 122.3 mA·h/g with an outstanding capacity retention of 99.1%.These excellent electrochemical properties can be attributed to the unique structure of NPC;it features hierarchical porosity with abundant carbon edge defects and large specific surface areas.These results illuminate the potential application of jackfruit rags-derived porous carbon in SIBs.
机译:可再生生物质衍生碳材料由于其出色的导电性,分层多孔结构,固有杂原子掺杂和环境友好性,成为钠离子电池(SIB)等电化学储能设备的有希望的电极材料,已引起越来越多的研究关注。在这里,我们研究了通过波峰热解法从菠萝蜜碎布衍生出的分级N掺杂多孔碳(NPC)作为SIBs阳极材料的潜力.NPC在1 A / g的2000次循环下的循环性能具有稳定的可逆容量。 122.3 mA·h / g,具有99.1%的出色容量保持率。这些优异的电化学性能可归因于NPC的独特结构;具有层级孔隙率,丰富的碳边缘缺陷和大的比表面积。这些结果为潜在的应用提供了启示。 SIB中菠萝蜜碎屑衍生的多孔碳的制备。

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  • 来源
    《天津大学学报(英文版)》 |2019年第5期|429-436|共8页
  • 作者单位

    CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences,Fuzhou 350002, China;

    University of Chinese Academy of Sciences, Beijing 100049,China;

    CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences,Fuzhou 350002, China;

    CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences,Fuzhou 350002, China;

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