利用XRD、SEM-EDS和DSC-TG技术研究了添加Na2O的CaO-Al2O3-SiO2体系中铝酸钙的形成规律.结果表明,当Al2O3与SiO2的质量比为3.0、CaO与Al2O3的摩尔比为1.0时,在1350℃烧结后的熟料主要由12CaO·7Al2O3、2CaO·Al2O3·SiO2和2CaO.SiO2组成.熟料中12CaO·7A12O3的含量随着Na2O的增加而增加,2CaO.Al2O3.SiO2的含量随着Na2O的增加而降低.Na2O在12CaO·7Al2O3中形成固溶体,增加了其单位晶胞体积.DSC分析表明,Na2O不仅促进了12CaO.7Al2O3的形成,而且使C12A7的形成温度降低了30℃.烧结熟料中的氧化铝溶出性能随着Na2O的增加而大幅度提高.%The formation characteristics of calcium aluminates in the CaO-AI2O3-SiO2 system with sodium oxide was investigated by XRD,SEM-EDS and DSC-TG technologies.The main phases in the clinker after sintering at 1350 ℃ are 12CaO·7Al2O3,2CaO·Al2O3·SiO2 and 2CaO·SiO2 when the mass ratio of Al2O3 to SiO2 is 3.0 and the molar ratio of CaO to Al2O3 is 1.0.The proportion of 12CaO·7Al2O3 increases with the increase of Na2O addition when the molar ratio of Na2O to Al2O3 is from 0 to 0.4,while the proportion of 2CaO·Al2O3·SiO2 decreases with the increase of Na2O addition.Na2O forms solid solution in 12CaO·7Al2O3,which increases the volume of elementary cell of 12CaO·7Al2O3.The formation temperature of 12CaO·7Al2O3 is decreased by 30℃ when the molar ratio of Na2O to Al2O3 increases from 0 to 0.4 determined by DSC.The alumina leaching property of clinker increases obviously with the increase of Na2O addition.
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