This paper introduces generation, recent development, and applications in crown ether chemistry. The structure features and characteristics of various new-type crown ethers are reviewed emphasizing on the subjects of synthesis, metal complex synthesis, selective complexation, self-assembly, complexation, and catalysis. Future applications are prospected with the expectation of more significant developments.%简要介绍了冠醚的结构、性能,冠醚化学的产生、发展及应用.重点介绍了:①新型冠醚及其金属配合物的合成;②新型冠醚的选择性络合及其自组装;③新型冠醚的络合作用及催化作用.并展望了其广阔的应用前景.
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