In this paper,acrylic compounds and C5 were adopted as raw materials,and tert-butyl catechol and [Cu2(dppm)2(C7H7N)(μ-NO3)](NO3) were selected as catalysts to synthesis norbornene and its derivates. Ex-perimental research have shown that the target products were obtained through the Diels-Alder reaction between cy-clopentadiene in C5 and acrylic compounds with 74.1% ~87.8% yield at the temperature of -15℃ ~5℃.%选取叔丁基邻苯二酚和[Cu2(dppm)2(C7H7N)(μ-NO3)](NO3)为催化剂,丙烯类化合物和混合碳五为原料合成降冰片烯衍生物.研究表明,在-15℃ ~5℃ 温度下,混合碳五中的环戊二烯和丙烯类化合物经Diels-Alder反应得到目标产物,收率可达74.1% ~87.8%.
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