化学氧化聚合制备微/纳米结构聚苯胺研究进展

摘要

Various approaches to the synthesis of many novel polyaniline microano structures reported in recent years can be considered as making efforts to control the nucleation and agglomeration of the polymerization products or af-fect the polymerization reaction itself. The present paper summarized the factors which influence the formation of polyani-line microano structures from three aspects, i.e. growth and agglomeration of the polymerization products, the oxidants to initiate the aniline chemical oxidation polymerization and the dopants existing during polymerization.%近年来多种见诸报道的新颖聚苯胺(PANI)微/纳米结构及其制备途径,可大体归为:主要控制了苯胺化学氧化聚合中聚合产物成核、生长过程或对聚合反应施加了影响.主要从聚合产物的生长和团聚、苯胺化学氧化聚合所用氧化剂和掺杂剂三方面归纳了制备微/纳米结构PANI的反应条件及其影响因素.