金属卟啉络合物催化氧化烷烃的研究概况

摘要

Recent researches of metalloporphyrin as an efficient catalyst for alkane oxidative conversion are reviewed with the emphasis on iron porphyrin with halogen substituents, which are more robust than the others. The catalytic mechanisms and molecular structure of metalloporphyrin are also mentioned.%详尽阐述了卟啉金属络合物催化氧化低级烷烃的研究情况，尤其是对多卤代卟啉金属络合物的构型转变和反应机理作了简明论述。