The physical and chemical properties of the newly synthesized reagent 4-Methoxy-3-sulfobenzenediazoaminoazobenzene and its highly sensitive color reaction with Cd(Ⅱ)have been studied.In the presence of Triton X-100,MeOSDAA reacts withCd(Ⅱ)to form a stable orangered complex with molar ratio of 2:1 in Na2B4O7-NaOH buffer solution(pH=9.5~11.6).The apparent molar absorptivity is 7.56×104L·mol-1·cm-1 at the maximun absorption wavelength of 540nm.Beer's law is obeyed in the concentration range of 0~10μg Cd(Ⅱ)in 25mL solution.%文章合成了4-甲氧基-3-磺酸基苯基三氮烯试剂,研究了它的物理和化学性质及其与镉(Ⅱ)的灵敏显色反应。在Triton X-100的存在下,于pH=9.5~11.6的硼砂-氢氧化钠的缓冲溶液中,显色剂与镉(Ⅱ)形成2∶1的红色配合物,最大吸收波长为540nm,表观摩尔吸光系数为7.56×104L.mol-1.cm-1,镉含量在0~10μg/25mL范围内遵守比耳定律。
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