硫酸铜酸性镀铜法制备铜-康铜热电堆的最佳实验条件研究

摘要

Thermopile is a common heat flow sensor,and the plating effect of thermopile affect its performance directly.This paper based on the basic principles of copper sulfate acid copper plating,and preparing thermopile through the electroplating of copper in constantan substrate,to study the effect of plating time,copper sulfate concentration,sulfuric acid concentration,electroplate solution temperature and current density on the thermoelectric potential of the thermopile.The results show that the optimal conditions for plating： plating time 20 min,copper sulfate concentration of 250 g/L,sulfuric acid concentration of 60 g/L,electroplate solution temperature 36 ℃,current density 10 A/dm2.Under these conditions,the thermoelectric potential of copper-constantan thermopile reaches the maximum.%热电堆是一种常见的热流传感器,热电堆的电镀效果直接影响其性能。基于硫酸铜酸性镀铜基本原理,通过在康铜基体上电镀铜的方式制备热电堆。研究了电镀时间、硫酸铜浓度、硫酸浓度、溶液温度、电流密度对热电堆输出热电势的影响。结果表明,最佳电镀条件为：电镀时间20 min,硫酸铜浓度250 g/L,硫酸浓度60 g/L,镀液温度36℃,电流密度10 A/dm2。在此条件下制备的铜-康铜热电堆输出热电势最高。