内壳层电子激发诱发的电子波函数的塌缩

摘要

利用Hartree-Fork（HFR）自洽场方法，计算了Ar原子在激发态3p53d 和激发态1s3p53d 4s、2s3p53d 4s、2p53p53d 4s、3s3p53d 4s、3p43d 4s情况下3d电子的轨道半径、有效量子数、束缚能及径向波函数，揭示了内壳层电子激发导致的电子波函数的塌缩现象。%Self-consistent-field calculations of the 3 d-orbital radii and binding energy and radial wave function of the subshell electrons in excited configurations 3p53d and 1s3p53d 4s, 2s3p53d 4s, 2p53p53d 4s, 3s3p53d 4s, 3p43d 4s in Argon have been made by using relativistic Hartree -Fork(HFR).The col-lapse effects induced by excitation of inner subshell electrons have been studied .