可见光响应型Pt/GaP纳米粉体的光催化性质

摘要

Gallium phosphide (GaP) nanoparticle was synthesized by the reaction of sodium phosphide and gallium chloride in dimethylbenzene. GaP-supported platinum photocatalysts, Pt(0.80wt%)/GaP and Pt(4.2wt%)/ GaP nanoparticles, were prepared by the simple reduction of chloroplatinic acid (H2PtCl6) with hydrazine hydrate (N2R·H2O). The photocatalytic activities of GaP and Pt/GaP nanoparticles for the decomposition of crystal violet were investigated under visible light irradiation. The results indicate that GaP, Pt(0.80wt%)/GaP and Pt(4.2wt%)/GaP nanoparticles can harness visible light to decompose crystal violet in aqueous solution. The photocatalytic activity of Pt(0.80wt%)/GaP is better than that of GaP while the photocatalytic activity of GaP is better than that of Pt(4.2wt%)/GaP. The Pt coverage has an important effect on the photocatalytic activity of Pt/GaP nanoparticles.%利用水合肼液相还原法在纳米磷化镓(GaP)粉体表面沉积贵金属铂(Pt),制备低Pt担载量Pt(0.80 wt%)/GaP和高Pt担载量Pt(4.2wt%)/GaP纳米粉体样品.在可见光照射条件下,分别以Gap和Pt/GaP纳米粉体作为光催化剂,对结晶紫水溶液进行光催化降解.实验结果表明,Gap和Pt/Gap两种纳米粉体皆具有可见光响应光催化性能;Pt担载量对Pt/GaP纳米粉体的光催化性能有着较大的影响,低Pt担载量Pt(0.80 wt%)/GaP纳米粉体的结晶紫光催化脱色率高于GaP纳米粉体,而高Pt担载量Pt(4.2 wt%)/Gap粉体的结晶紫光催化脱色率则低于GaP纳米粉体.