手性杯芳烃化合物的合成及催化性能研究

摘要

杯芳烃是一类由苯酚和甲醛缩合的含有洞穴的大环化合物。作为第三代主体化合物,其在分子识别,模拟酶催化,自组装等领域的研究取得了很大进展。近年来,特别是手性杯芳烃由于其特殊的结构,在不对称催化领域更是引起了人们的极大重视和兴趣。文章合成了几种手性杯芳烃化合物并对其在催化性能方面作了一些研究。%This thesis is mainly focused on the structure and the synthetic methods of chiral calixarene,Calixarenes are a class of marcrocycles derived from the condensation of phenols and formaldehyde.As the third generation host compounds,the study of them in the fields such as molecule recognition,assemble and enzyme mimics has been made great progress.In these years,the chiral calixarenes attract increasing interesting in asymmetric catalysis because of their special conformation.