合成光学活性菊酸酯的方法

摘要

L-Menthanol ester of chiral chrysanthemic acid was obtained via stereoselective esterification of the racemic acid, and the result was analyzed by MOPAC. Promoted by the above phenomenon, we obtained L-menthol ester of chiral chrysanthemic acid via the isomerization of L-menthol ester of racemic chrysanthemic acid.%L-孟醇与过量外消旋菊酰氯反应表现出非对映异构体选择性,得到了光学活性菊酸的L-孟醇酯.由外消旋菊酸的L-孟醇酯经异构化反应也得到了光学活性菊酸的L-孟醇酯.