A series of new five-ring-fused dithiophene-dione derivatives were successfully synthesized by Suzuki coupling reaction, saponification, acylation, intramolecular Friedel- Crafts cyclization from sodium 5-alkylthiophen-2-yl boronate. The structures were characterized by NMR, IR, MS and elemental analysis.%以烷基噻吩硼酸钠盐为起始原料,经Suzuki偶联反应、皂化反应、酰基化反应、分子内Friedel-Crafts成环等反应,成功地合成了一系列新型并噻吩五元杂环酮类衍生物,其结构经NMR,IR,MS和元素分析表征.
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