Synthesis and Crystal Structure of Complex Cdq3Cd(qH)3(ClO4)CH3OH(q = 8-Quinolinolate, qH = 8-Quilinolinol)

摘要

The mono-nuclear complex [Cdq3][Cd(qH)3](ClO4)CH3OH has been synthesized by 8-quinolinol and hydrated cadmium perchlorate in methanol solution.The crystal belongs to = 88.497(2), γ= 75.681(2)°, V = 2534.1(6)(。A)3, Z = 1, C11oH86Cd4Cl2 N12O22, Mr = 2448.41, Dc =1.604 g/cm3, F(000) = 1232 andμ = 0.961 mm-1.The structure was refined to R = 0.0387 and wR =0.0973 for 7775 observed reflections (I ＞ 2σ(I)).In this crystal there exist two independent mononuclear complexes of [Cdq3] and [Cd(qH)3]2+.Each cell contains two [Cdq3]- anions, two [Cd(qH)3]2+ cations, two ClO4- anions and two methanol molecules.