二维配合物Cd3(HBTA)2(BIPA)3n的水热合成、晶体结构和荧光性质研究

摘要

The hydrothermal reactions of 5-bromoisophthalic acid(H2BIPA),benzotriazole(HBTA)with Cd(NO3)2·4H2O in basified solvent gave rise to a coordination polymer[Cd3(HBTA)2(BIPA)3]n(1),which has been characterized by elemental analysis,IR and single-crystal X-ray diffraction.Complex 1 presents a two-dimensional(2D)layer network containing the edge-sharing 1D-O-Cd-O chains through repetitions of the alternating arrangement of the Cd3(CO2)6 cluster and displays strong luminescent emission at room temperature.CCDC: 775284.