动力学机理函数的导出途径、逻辑选择／确定及在含能材料分解反应速率方程中的一些应用

摘要

The common kinetic mechanism functions were derived ,which include the diffusion mechanism function , the random nucleation and the subsequent growth mechanism function ,the power law mechanism function ,the phase boundary reaction mechanism function and the chemical reaction mechanism function .The technical approach for logical selection and determination of the most probable mechanism function was presented .The function mecha‐nisms of decomposition reaction of some energetic materials were collected and expatiated .The mechanism function and rate equation of the exothermic decomposition reaction process of 6b‐nitrohexahydro‐2H‐1 ,3 ,5‐trioxacyclopenta [cd]‐pentalene‐2 ,4 ,6‐triyl trinitrate (NHTPN) are reported with 79 references .%推演了包括扩散机理函数、随机成核和随后生长机理函数、幂函数法则机理函数、相边界反应机理函数和化学反应机理函数在内的常用动力学机理函数。提出了逻辑选择／确定最可几机理函数的技术途径。汇集、阐述了一些含能材料分解反应的机理函数。报道了描述6b‐硝基‐1，3，5‐三氧环戊烷[cd]‐并环戊二烯‐2，4，6‐三硝酸酯（NHTPN）放热分解反应过程的机理函数和速率方程。附参考文献79篇。