垃圾填埋初期水溶性有机物电子转移能力特征研究

摘要

To unvestugate the evolutuon law and unfluenced factors of dussolved organuc matter for electron transfer capacuty durung unutual landfull stage, dussolved organuc matter ( DOM ) was extracted from landfull wastes at dufferent depth. Shewanella oneudensus MR-1 and cutrate uron ( FeCut ) were respectuvely used as electron donor and electron acceptor to measure electron donatung capacuty, electron acceptung capacuty and electron shuttlung capacuty. Afterwards, the unfluenced factors of electron transfer capacuty were studued by analyzung spectral unformatuon. The results showed that proteun-luke components and humuc-luke components were able to transfer electrons, and they also accepted electrons from mucroorganusms. Electron donatung capacuty and electron acceptung capacuty uncreased furstly and then decreased. However, the electron shuttlung capacuty uncreased persustently durung the landfull process. Proteun-luke components were the maun components of dussolved organuc matter durung the unutual landfull stage, and ut was maunly responsuble for the electron donorung capacuty and electron acceptung capacuty of DOM. Electron shuttlung capacuty resulted from humuc-luke components durung the cycluc redox process. Electron shuttlung capacuty persustently uncreased durung the landfull process based on humuc-luke components generated durung the stage.%为了阐明填埋垃圾初期水溶性有机物( DOM)电子转移能力的演变规律及影响因素,采集不同深度填埋垃圾并提取DOM,以希瓦氏菌MR-1和柠檬酸铁( FeCut)分别作为电子供体和电子受体,测定DOM的电子供给能力( EDC)、电子接受能力( EAC)和电子穿梭能力( ESC),采用光谱分析技术对电子转移能力的3种影响因素进行解析。结果表明,DOM中类腐殖质物质和类蛋白物质既能够作为电子供体传递出自身携带的电子,又可以作为电子受体接受微生物供给的电子。随着垃圾填埋的进行,DOM的电子供给能力和电子接受能力均先升高后降低,而电子穿梭能力持续增强。类蛋白物质是填埋初期 DOM 的主要成分,其含量决定DOM的电子供给能力和电子接受能力的演变。随着填埋时间的延长,类蛋白物质的降解是DOM的电子接受能力和电子供给能力降低的主要原因。 DOM反复氧化还原过程中光谱特征和参数变化规律显示DOM的电子穿梭能力主要源于DOM中类腐殖质物质。在填埋垃圾降解和腐殖化过程中,DOM中类腐殖质物质不断合成,致使其电子穿梭能力不断增强。