The stereoselective synthesis of (+)-preussin has been achieved by utilizing the Sharpless asymmetric epoxidation of the divinylcarbinol(3) and the oxidative cyclization of 9with PDC as the key steps.
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机译:stereoselective synthesis of (2 Z,4 E)-2,4-pentadien-1-ols via sequential 1,4-elimination reaction and [1,2]-wittig rearrangement starting from (E)-4-alkoxy-2-butenyl benzoates